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Rate of Reaction

Rate of Reaction

This lesson aligns with Next Generation Science Standards (NGSS) PS1.B

Introduction 
A chemical reaction is a process that occurs when two or more substances react chemically and form a new substance. The substances that are initially involved are known as reactants, whereas the substances that are present at the end of the reaction are known as products. Matter and energy are conserved during a chemical reaction. Examples of chemical reactions in everyday life are cooking, digesting food, photosynthesis, etc. The rate of reaction refers to the speed at which a chemical reaction proceeds.  The rate of reaction depends on and is affected by some factors, such as temperature, pressure, and the concentrations of the reactants. In this article, we will discuss the rate of reaction and factors that affect the rate of reaction.

Rate of Reaction
The rate of reaction is the speed at which reactants are converted to products in a chemical reaction. The rate of reaction varies by a great deal. Some chemical reactions are completed in seconds and are easy to observe, while others take some time to reach the final product and are much slower. For example, the combustion of wood has a high rate of reaction as the process is fast, and rusting of iron has a low rate of reaction as it takes some time to reach the final equilibrium.

Factors that Affect the Rate of Reaction
The various factors that can affect the reaction rate are listed below:

Nature of the Reaction
The type and nature of the reaction highly affect the reaction rate. As mentioned above, some reactions are fast, while others take some time to complete, and the process is very slow. The reaction rate is affected by the physical state of reactants, e.g., the reaction rate is slower in liquids than in gases, and the rate of reaction is slower in solids than liquids.

The number of reactants and complexity of the reaction also influence the rate of reaction. The size of the reactants also plays an important role. As the size of the reactants gets smaller, a higher rate of chemical reaction will be observed. 

Effect of Concentration on Reaction Rate
According to the law of mass action, the rate of a chemical reaction is directly proportional to the concentration of the reactants. The reaction rate increases with the increase in the concentration of the reactants, and the rate of reaction decrease with the decrease in the concentration of the reactants.

Pressure Factor
If the pressure of gaseous reactants is increased, the collisions among the particles of reactants also increase. Consequently, the rate of reaction is increased. The higher the pressure of the reactants, the faster the reaction will be.

Temperature Factor
When the temperature of the reactants increases, the average kinetic energy of the reactant molecules also increases. The reactant molecules move quickly and collide more often. As a result, the rate of a chemical reaction becomes fast.

Solvent
The ionic strength and solvent properties also affect the chemical reaction rate.

Presence of a Catalyst 
A catalyst is a substance that increases the rate of reaction without actually participating in a chemical reaction. The presence of a catalyst increases the reaction rate by providing an alternative pathway.

The Surface Area of the Reactants 
The surface area of the reactants surely affects the rate of reaction. When the surface area of the reactants is increased, the chance of collision among the particles also increases. This is because more particles are now exposed to one another. As a result, the rate of reaction increases.

Summary 
  • A chemical reaction is a process in which reactant bonds are broken, and new bonds are formed between the products.
  • The rate of reaction generally refers to the rate at which products are formed from the reactant molecules in a chemical reaction.
  • The rate of reaction is highly affected by the nature of the reactants. The number of reactants, the reactant's complexity, and the reactant's size also influence the reaction rate.
  • Some chemical reactions have a high rate of reaction while others have a low rate of reaction, e.g., burning of paper is a fast process as compared to rusting of iron.
  • The reaction rate also increases as the reactant's temperature and pressure increase. The reaction rate increases as the reactant's concentration increases and vice versa.
  • The presence of a catalyst also speeds up a chemical reaction. The solvent's properties and the reactant's surface area also influence the rate of reaction.
 

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